In the article by V. A. Kalyavin, T. A. Smolina, and O. A. Reutov, “On the monomolecular mechanism of the isotopic exchange of benzylmercury halides with radioactive mercuric halide,” published in *DAN*, vol. 156, no. 1, 1964:
due to structural factors:
Submitted 1964-01-01 | RussiaRxiv: ru-196401.87281 | Translated from Russian

Abstract

Full Text

CORRECTION

In the article by V. A. Kalyavin, T. A. Smolina, and O. A. Reutov, “On the monomolecular mechanism of the isotopic exchange of benzylmercury halides with radioactive mercuric halide,” published in DAN, vol. 156, no. 1, 1964:

  1. On p. 96, lines 1 and 2, it should read:

due to structural factors:

\[ \gamma \leftarrow \begin{array}{c} \text{benzene ring} \end{array} \leftarrow \overset{\cdot}{\mathrm{C}}\mathrm{H}_2^{(-)} \quad {}^{(+)}\mathrm{HgBr} \]

  1. On p. 96, in the reaction-mechanism scheme, it should be:

\[ \mathrm{O_2N{-}} \begin{array}{c} \text{benzene ring} \end{array} {-}\mathrm{CH_2{-}}{}^{203}\mathrm{HgBr} \ \xrightleftharpoons[\text{fast}]{\text{slow}}\ \mathrm{O_2N{-}} \begin{array}{c} \text{benzene ring} \end{array} {-}\overset{\cdot}{\mathrm{C}}\mathrm{H}_2^{(-)} \quad {}^{(+)\,203}\mathrm{HgBr} \]

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Submission history

In the article by V. A. Kalyavin, T. A. Smolina, and O. A. Reutov, “On the monomolecular mechanism of the isotopic exchange of benzylmercury halides with radioactive mercuric halide,” published in *DAN*, vol. 156, no. 1, 1964: